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Enantioselective man made equipment are usually not purely within the leading edge of chemical and pharmaceutical examine yet job during this sector is continually expanding. it's motivated by means of the urgency to procure medicines or compounds of medicinal curiosity as unmarried anantiomers, and the keeness to synthesize ordinary items in nonracemic shape. This quantity offers seven chapters from pioneers and professionals during this speedily increasing box.

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8. -P; Nakai, T. J. Am. Chem. Soc. 1990,112, 6737. 9. ; Nakai, T. J. Org. Chem. 1991,56, 2952. 10. ; Takita, T. J. Antibiot. ; Takita, T; Iitaka, Y. J. Antibiot. ; Takita, T. Takeuchi, T. J. Antibiot. 1987,40,1077. 11. ; Kato, K; Takita, T. Tetrahedron Lett. 1988, 29, 4739,4743; Norbeck, D. ; Kramer, J. B. J. Am. Chem. Soc. ; Kato, Asymmetric Carbonyl-Ene Reactions 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. ; Yamamura, S. Tetrahedron Lett. 1990,31,119 and references cited therein.

3, p. 191. 55. Relative asymmetric induction on the basis of chelation control has been, so far, of singular importance for predictable remote stereocontrol. For leading references, see: Molander, G. , J. P. J. Am. Chem. Soc. 1991,113, 3608. 56. ; Terada, M. J. Am. Chem. Soc. 1992,114,6566; 1992, 114, 9242. 57. Whitesell, J. ; Allen, D. E. J. Org. Chem. 1985,50, 3025. 58. Whitesell, J. ; Allen, D. E. J. Am. Chem. Soc. 1988,110, 3585. 59. Whitesell, J. ; Minton, M. A. J. Am. Chem. Soc. 1986,108, 6802.

Synth. Org. , Jpn. 1990,48, 292. 3. Reviews: Snider, B. B. Ace. Chem. Res. 1980,13, 426; Snider, B. B. ; Kluwer Academic Publishers: London, 1989; pp. 147-167. 4. Reviews: (a) Hoffmann, R. W. Angew. Chem. Int. Ed. Engl. ; Seebach, D. Angew. Chem. Int. Ed. Engl. 1983,22,31; (c) Yamamoto, Y. Ace. Chem. Res. 1987, 20, 243; (d) Hoffmann, R. W. Angew. , Int. Ed. Engl. 1987, 26, 489; (e) Roush, W. R. In Comprehensive Organic Synthesis', Trost, B. ; Fleming, I. ; Pergamon: Oxford, 1991; Vol. 2, p. 1; (f) Marshall, J.

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